Boron

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Image

Attribution: James L Marshall, University of North Texas

Animated Boron

History

From the Arabic word Buraq, Persian Burah. Boron compounds have been known for thousands of years, but the element was not discovered until 1808 by Sir Humphry Davy and by Gay-Lussac and Thenard.

Sources

The element is not found free in nature, but occurs as orthoboric acid usually found in certain volcanic spring waters and as borates in boron and colemantie.

Important sources of boron are ore rasorite (kernite) and tincal (borax ore). Both of these ores are found in the Mojave Desert. Tincal is the most important source of boron from the Mojave. Extensive borax deposits are also found in Turkey.

Boron exists naturally as 19.78% 10B isotope and 80.22% 11B isotope. High-purity crystalline boron may be prepared by the vapor phase reduction of boron trichloride or tribromide with hydrogen on electrically heated filaments. The impure or amorphous, boron, a brownish-black powder, can be obtained by heating the trioxide with magnesium powder.

Boron of 99.9999% purity has been produced and is available commercially. Elemental boron has an energy band gap of 1.50 to 1.56 eV, which is higher than that of either silicon or germanium.

Uses

Amorphous boron is used in pyrotechnic flares to provide a distinctive green color, and in rockets as an igniter.

By far the most commercially important boron compound in terms of dollar sales is Na2B4O7 • 5H2O. This pentahydrate is used in very large quantities in the manufacture of insulation fiberglass and sodium perborate bleach.

Boric acid is also an important boron compound with major markets in textile products. Use of borax as a mild antiseptic is minor in economical terms. Boron compounds are also extensively used in the manufacture of borosilicate glasses. Other boron compounds show promise in treating arthritis.

The isotope boron-10 is used as a control for nuclear reactors, as a shield for nuclear radiation, and in instruments used for detecting neutrons. Boron nitride has remarkable properties and can be used to make a material as hard as diamond. The nitride also behaves like an electrical insulator but conducts heat like a metal.

Boron also has lubricating properties similar to graphite. The hydrides are easily oxidized with considerable energy liberation, and have been studied for use as rocket fuels. Demand is increasing for boron filaments, a high-strength, lightweight material chiefly employed for advanced aerospace structures.

Boron is similar to carbon in that it has a capacity to form stable covalently bonded molecular networks. Carbonates, metalloboranes, phosphacarboranes, and other families comprise thousands of compounds.

General Info

AtomicNumber
5
Symbol
B
Name
Boron

Atomic Info

Appearance
AtomicWeight
10.811(7)
Color
FFB5B5
ElectronicConfiguration
[He] 2s2 2p1
ElectronegativityInPauling
2.04
AtomicRadiusInPM
82
IonRadiusInPM
27 (+3)
VanDerWaalsRadiusInPM
IEinKJmol
801
EAinKJmol
-27
OxidationStates
1, 2, 3
StandardState
solid
BondingType
covalent network
MeltingPoint
2348
BoilingPoint
4273
Density
2.46
State
Metalloid
DiscoveredYear
1807