Thorium

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Animated Thorium

History

Morten Esmark found a black mineral on Løvøya island, Norway and gave a sample to his father Jens Esmark, a noted mineralogist. The elder Esmark was not able to identify it and sent a sample to Swedish chemist Jöns Jakob Berzelius for examination in 1828. In 1829 Berzelius determined that it contained a new element, which he named thorium after Thor, the Norse god of thunder. The metal had no practical uses until 1885 when Carl Auer von Welsbach invented the gas mantle. Thorium was first observed to be radioactive in 1898, independently, by Polish-French physicist Marie Curie and German chemist Gerhard Carl Schmidt. Between 1900 and 1903, Ernest Rutherford and Frederick Soddy showed how thorium decayed at a fixed rate over time into a series of other elements. This observation led to the identification of half-life as one of the outcomes of the alpha particle experiments that led to their disintegration theory of radioactivity. The crystal bar process (or "iodide process") was discovered by Anton Eduard van Arkel and Jan Hendrik de Boer in 1925 to produce high-purity metallic thorium. Because of health concerns, the thorium in classic lantern mantles has been replaced by rare-earth elements that also produce intense light without the radioactivity.

Sources

Thorium-232 is a primordial nuclide, having existed in its current form for over 4.5 billion years, a half-life is comparable to the age of the Universe and thus predating the formation of the Earth. Thorium was forged in the cores of dying stars through the r-process and scattered across the galaxy by supernovas. Thorium is found in small amounts in most rocks and soils. Soil commonly contains an average of around 6 parts per million (ppm) of thorium. Thorium occurs in several minerals including thorite (ThSiO4), thorianite (ThO2 + UO2) and monazite. Thorianite is a rare mineral and may contain up to about 12% thorium oxide. Monazite contains 2.5% thorium, allanite has 0.1 to 2% thorium and zircon can have up to 0.4% thorium.[66] Thorium-containing minerals occur on all continents. Thorium is now thought to be about three times as abundant as uranium and about as abundant as lead or molybdenum. Thorium is recovered commercially from the mineral monazite, which contains from 3 to 9% ThO2 along with rare-earth minerals.

Uses

The principal historic use of thorium has been in the preparation of the Welsbach mantle, used for portable gaslights. These mantles, consisting of thorium oxide with about 1% cerium oxide and other ingredients, glow with a dazzling light when heated in a gas flame. Thorium is an important alloying element in magnesium, imparting high strength and creep resistance at elevated temperatures. Because thorium has a low work-function and high electron emission, it is used to coat tungsten wire used in electronic equipment. The oxide is also used to control the grain size of tungsten used for electric lamps; it is also used for high-temperature laboratory crucibles. Glasses containing thorium oxide have a high refractive index and low dispersion. Consequently, they find application in high quality lenses for cameras and scientific instruments. Thorium oxide has also found use as a catalyst in the conversion of ammonia to nitric acid, in petroleum cracking, and in producing sulfuric acid. Thorium metal is a source of nuclear power. There is probably more energy available for use from thorium in the minerals of the earth's crust than from both uranium and fossil fuels. Any sizable demand from thorium as a nuclear fuel is still several years in the future. Work has been done in developing thorium cycle converter-reactor systems. Several prototypes, including the HTGR (high-temperature gas-cooled reactor) and MSRE (molten salt converter reactor experiment), have operated. While the HTGR reactors are efficient, they are not expected to become important commercially for many years because of certain operating difficulties.

Isotopes

Twenty-seven thorium radioisotopes have been characterized, with a range in atomic weight from 210 to 236. All are unstable with the most stable being 232Th with a half-life of 14.05 billion years. Thorium-232 represents all but a trace of naturally occurring thorium. It is an alpha emitter and goes through six alpha and four beta decay steps before becoming the stable isotope 208Pb. 232Th is sufficiently radioactive to expose a photographic plate in a few hours. Other isotopes of thorium are short-lived intermediates in the decay chains of higher elements, and only found in trace amounts. The longer-lived of these trace isotopes include: 230Th with a half-life of 75,380 years which is a daughter product of 238U decay; 229Th with a half-life of 7340 years and 228Th with a half-life of 1.92 years. All of the remaining radioactive isotopes have half-lives that are less than thirty days and the majority of these have half-lives less than ten minutes. Much of the internal heat the earth produces has been attributed to thorium and uranium.

General Info

AtomicNumber
90
Symbol
Th
Name
Thorium

Atomic Info

Appearance
AtomicWeight
232.03806(2)
Color
00BAFF
ElectronicConfiguration
[Rn] 6d2 7s2
ElectronegativityInPauling
1.3
AtomicRadiusInPM
IonRadiusInPM
94 (+4)
VanDerWaalsRadiusInPM
IEinKJmol
587
EAinKJmol
OxidationStates
2, 3, 4
StandardState
solid
BondingType
metallic
MeltingPoint
2023
BoilingPoint
5093
Density
11.72
State
Actinide
DiscoveredYear
1828